Top Historic Moments on Instagram: "On the 9th of July 2006, French captain Zinedine Zidane headbutted Italian defender Marco Materazzi in the chest during extra time of the FIFA World Cup final in Berlin. The incident, provoked by Materazzi's taunt about Zidane's sister after an earlier shirt exchange, occurred in the 110th minute with the score tied 1-1. Referee Horacio Elizondo, alerted by the fourth official, issued Zidane a straight red card, ejecting him from his final professional match.

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